An Extremely Porous Hydrogen-Bonded Framework Composed of d -Penicillaminato CoIII 2 AuI 3 Complex Anions and Aqua Cobalt(II) Cations: Formation and Stepwise Structural Transformation
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چکیده
منابع مشابه
An Extremely Porous Hydrogen-Bonded Framework Composed of d-Penicillaminato Co(III)2Au(I)(3) Complex Anions and Aqua Cobalt(II) Cations: Formation and Stepwise Structural Transformation.
A unique example of a hydrogen-bonded ionic solid with a porosity of 80 %, [Co(H2O)6]3 [Co2Au3 (d-pen-N,S)6]2 (1; d-H2 pen=d-penicillamine), composed of [Co(H2O)6](2+) cations and [Co2Au3 (d-pen-N,S)6 ](3-) anions, is reported. Solid 1 was kinetically produced and was then transformed stepwise into two more thermodynamically stable solids with lower porosities, [Co(H2O)4 ][Co(H2O)6]2 [Co2Au3 (d...
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ژورنال
عنوان ژورنال: Chemistry - An Asian Journal
سال: 2015
ISSN: 1861-4728
DOI: 10.1002/asia.201501352